Concrete Allure Thermodynamic Processes for an Ideal Gas

14 July 12:38

    =frac ;

    |-

    | Work

eginw=-int_^ PdV end

| align=center |

-Pleft ( V_2-V_1 
ight );

| align=center |

0;

| align=center |

-nRTlnfrac;

| align=center |

C_vleft ( T_2-T_1 
ight );

|-

| Calefaction Capacity,

C;

| align=center |

C_p = (5/2)nR;

| align=center |

C_v = (3/2)nR ;

| align=center |

C_p;

C_v;

| align=center |

C_p;

C_v;

|-

| Centralized Energy,

Delta U = 3/2 | align=center | q+w;

q_p+PDelta V;

| align=center |

q;

w=0;

C_vleft ( T_2-T_1 
ight );

| align=center |

0;

q=-w;

| align=center |

w;

q=0;

C_vleft ( T_2-T_1 
ight );

|-

| Enthalpy,

Delta H;

H=U+PV;

| align=center |

C_pleft ( T_2-T_1 
ight );

| align=center |

q_v+VDelta P;

| align=center |

0;

| align=center |

0;

    |-

    | Entropy

eginDelta S=-int_^ frac dT end

| align=center |

C_plnfrac;

| align=center |

C_vlnfrac;

| align=center |

nRlnfrac;

| align=center |

0;

    |}

    ^Table create by a analysis apprentice in CHEM382 (Physical Allure II) at the U. of Cincinnati (circa 2006)

    We are accustomed that the molar Gibbs chargeless activity of an ideal is

ar G = ar G^circ+RT lnfrac;

. Lets try and acquire

ar U=ar U^circ=ar H^circ-RT;

; acquainted that

ar U^circ=ar G^circ+Tar S^circ-RT;

and bold that the centralized activity

U;

and enthalpy

H;

of an ideal gas are absolute of burden and volume.

Tags: energy, ideal, processes, center, align

center, align, ight, ideal, energy, vleft, chemistry, physical, , align center, ideal gas, physical chemistry, ar u^circ ar, end| align center, chemistry thermodynamic processes, physical chemistry thermodynamic,

Share Concrete Allure Thermodynamic Processes for an Ideal Gas: